Transition probabilities of a string oscillator subject to impulsive collisions with a heavy mass point.

نویسنده

  • Max Teubner
چکیده

Impulsive linear collisions between a string oscillator (a one-dimensional particle in a box) and a mass point are studied quantum mechanically. In the limit of a very heavy mass point (which corresponds classically to many collisions during a single encounter) the transition probabilities are determined exactly. The result permits a discussion of the mixed quantum-classical regime where the collider becomes almost classical while the oscillator remains quantum mechanical. While the average transition probabilities P(m-->n) are well reproduced by the Ehrenfest mean-field approximation, the prediction for the superimposed high-frequency resonance structure is qualitatively wrong for a genuine quantum oscillator. Only if the oscillator is also almost classical and if (m-n)2 square root(mu) << m, where mu is the mass ratio collider/oscillator, this structure is correctly predicted by the Ehrenfest approximation.

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عنوان ژورنال:
  • The Journal of chemical physics

دوره 123 17  شماره 

صفحات  -

تاریخ انتشار 2005